"The player has begun treatment and the estimated recovery time is approximately three weeks," Valencia said in a statement on their website (www.valenciacf.com).
Valencia will miss Rami's solid presence in defence and he also scored the club's 90th-minute goal in last week's first leg, which finished 2-1 to PSG.
Victor Ruiz is likely to partner Ricardo Costa in central defence in Rami's absence.
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