Uefa have confirmed the match dates and kick-off times for the Reds after they were drawn in Group A on Friday.
None of Liverpool’s six group games have been allocated in the early evening kick-off slot.
After heading to Italy, Ajax and Rangers visit Anfield with the reverse fixture at Ibrox starting the second half of the group stage. A trip to Amsterdam rounds off the away days for Jurgen Klopp’s men before Napoli head to Merseyside in early November.
Here are all the details for Liverpool’s group stage...
Liverpool Champions League group stage dates and kick-off times (all times BST)
Wednesday, September 7: Napoli vs Liverpool, 8pm
Tuesday, September 13: Liverpool vs Ajax, 8pm
Tuesday, October 4: Liverpool vs Rangers, 8pm
Wednesday, October 12: Rangers vs Liverpool, 8pm
Wednesday, October 26: Ajax vs Liverpool, 8pm
Tuesday, November 1: Liverpool vs Napoli, 8pm