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Unai Emery - who Jurgen Klopp has hailed as the ‘king of the cups’ - has already seen his side conquer Juventus and Bayern Munich en route to the final four and the former Arsenal boss looks tailor-made for these occasions.
Liverpool, of course, will be favourites and could yet win a stunning quadruple but know Villarreal will make like as difficult as possible for them.
With the first leg up at Anfield this evening, however, they can surely be confident of taking some sort of lead to Spain next week.
Here’s everything you need to know about where to watch tonight’s game...
Where to watch Liverpool vs Villarreal
TV channel: In the UK, tonight’s game will be broadcast live on BT Sport 2 and BT Sport Ultimate. Coverage begins at 7pm BST ahead of an 8pm kick-off.
Live stream: BT Sport subscribers will also be able to watch the match online via the website or BT Sport app.
LIVE coverage: Get minute-by-minute updates through Standard Sport’s dedicated match blog. Malik Ouzia will be providing expert analysis from Anfield.