The visitors can expect a warm reception in the capital as they look to secure a morale-boosting run to a major tournament amid such turmoil back home.
On the pitch, things are going rather well for the Three Lions following a win in Italy on Thursday night that put them in good shape for reaching next summer’s tournament.
England have also only ever lost once to Ukraine with this evening’s clash free to watch on terrestrial television.
Where to watch England vs Ukraine
TV channel: In the UK, the game will be televised live and free-to-air on Channel 4, with coverage starting at 4pm for a 5pm GMT kick-off.
Live stream: Fans can also catch the contest live for free online via the All4 website and app.
Live blog: You can follow all the action on matchday via Standard Sport’s live blog, with expert analysis from our reporters at the ground.